Liquid-Liquid Interfacial Tension of Electrolyte Solutions

Interfacial Tension of Electrolyte Solutions

A theory is presented to account for the increase in surface tension of water in the presence of electrolyte. Unlike the original “grandcanonical” calculation of Onsager and Samaras, which relied on the Gibbs adsorption isotherm and lead to a result which could only be expressed as an infinite series, our approach is “canonical” and produces an analytic formula for the excess surface tension. F...

Curvature dependence of the electrolytic liquid-liquid interfacial tension.

The interfacial tension of a liquid droplet surrounded by another liquid in the presence of microscopic ions is studied as a function of the droplet radius. An analytical expression for the interfacial tension is obtained within a linear Poisson-Boltzmann theory and compared with numerical results from nonlinear Poisson-Boltzmann theory. The excess liquid-liquid interfacial tension with respect...

Modeling Interfacial Tension in Liquid−Liquid Systems Containing Electrolytes

A comprehensive model has been developed for calculating the interfacial tension (σ) in liquid−liquid systems with or without electrolyte components. The model consists of an equation for computing the interfacial tension of two-liquidphase nonelectrolyte systems and an expression for the effect of the electrolyte concentration. The dependence of the interfacial tension on the electrolyte conce...

Molecular simulations of solid-liquid interfacial tension of silicon.

Prediction of Surface Tension in Single and Mixed Electrolyte Solutions